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Quantitative Analysis of Copolymers using a Pyroprobe

Analytical pyrolysis is a powerful tool for the qualitative analysis of polymers. The analysis usually starts from a simple pyrogram match to an existing pyrolysis database to identify the polymer chemical structure. If multiple polymers are identified, a quantitative method is often adopted by comparing peak areas of the pyrolysis products to determine each polymer ratio. In this application, styrene-isoprene block copolymers, which are large-volume, lowcost, commercial thermoplastic elastomers, are analyzed by following this approach.

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