Measurements of absolute molecular weight of synthetic polymers
In this application note, we'll describe the successful molecular weight measurement of a polystyrene, PMMA and PVC sample using the OMNISEC system. This instrument can accurately measure the absolute molecular weight of any polymers independent of elution volume or structure. Although the measurements here have been performed using simple polymers, these methods can be applied to any polymer measured by GPC.
Measurements of absolute molecular weight of synthetic polymers
In this application note, we'll describe the successful molecular weight measurement of a polystyrene, PMMA and PVC sample using the OMNISEC system. This instrument can accurately measure the absolute molecular weight of any polymers independent of elution volume or structure. Although the measurements here have been performed using simple polymers, these methods can be applied to any polymer measured by GPC.
Introduction
Malvern's OMNISEC system is an advanced multi-detector GPC system that combines light scattering, refractive index (RI), ultraviolet (UV) and intrinsic viscosity (IV) detectors to generate a large amount of information about a sample simultaneously.
The physical properties and behavior of polymers depends strongly on the properties of the polymer molecules themselves. Molecular weight and molecular weight distribution, molecular size and structure all affect how the material will behave. By understanding and controlling these properties, polymer manufacturers can control polymer production and quality.